Ethyl 8-amino-6-bromoimidazo[1,2-a]pyridine-2-carboxylate
نویسندگان
چکیده
There are two independent mol-ecules in the asymmetric unit of the title compound, C(10)H(10)BrN(3)O(2), which are linked by N-H⋯O and C-H⋯O hydrogen bonds. The fused ring systems in both mol-ecules are nearly planar with maximum deviations of 0.001 (3) and 0.029 (3) Å. All non-H atoms of the first mol-ecule are approximately co-planar whereas in the second mol-ecule, the ethyl group is almost perpendicular to the imidazo[1,2-a]pyridine system, the C-O-C-C torsion angles in the carb-oxy-lic acid ethyl group being -179.8 (4) and 112.1 (5)°, respectively.
منابع مشابه
Crystal structure of ethyl 5-[3-(dimethylamino)acryloyl]-2-{[(dimethylamino)methylidene]amino}-4-methylthiophene-3-carboxylate
In the title compound, C16H23N3O3S, the dihedral angles between the thio-phene ring and the almost planar di-methyl-amino-methyl-ene-amino (r.m.s. deviation = 0.005 Å) and di-methyl-amino-acryloyl (r.m.s. deviation = 0.033 Å) substituents are 6.99 (8) and 6.69 (7)°, respectively. The ester CO2 group subtends a dihedral angle of 44.92 (18)° with the thio-phene ring. An intra-molecular C-H⋯O hydr...
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